✦ LIBER ✦
Solvolytic studies of stereoisomeric tricyclo[4.2.0.02,4]octan-5-yl derivatives. Conformationally distinguishable cycloprophylcarbinyl cations and the reactivity consequences of differing orbital alignments
✍ Scribed by Leo A. Paquette; O. Cox; M. Oku; R.P. Henzel; J.A. Schwartz
- Book ID
- 104238233
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- French
- Weight
- 245 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
The accelerated solvolytic behavior of exo-and endo-bicyclo[3.l.O]alk-2-yl derivatives provides convincing evidence that comparable cyclopropyl participation accompanies ionization of both epimers. 2 The pair of isomers react at very similar rates (k,ndo/k+xo = 1.3-l.5 depending on the leaving group), the small discrepancy arising from ground state energy differ-