Photochemical synthesis of tetracyclo[3.3.0.02,4.03,7)octane
โ Scribed by Freeman, Peter K.; Ziebarth, Timothy D.
- Book ID
- 125959574
- Publisher
- American Chemical Society
- Year
- 1973
- Tongue
- English
- Weight
- 390 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0022-3263
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## Abstract Cyclooctatetraene is a common product of photolysis of the title compound la. Depending on reaction conditions it is accompanied by benzene (solvent: cyclohexane, ฮณ = 253.7 nm), benzene plus semibullvalene (acetone, 300 nm), and an oxetane (cyclohexane, 350 nm, presence of an equimolar
The interesting tetracyclo[4.3.0.02'4.03~7]nonane ring system, which serves as the basic structural unit for the mixture of nitrile epimers (I) obtained in the homo-Diele-Alder condensation of acrylonitrile with norbornadieoe,has not been extensively studied due to the low yields previously encounte