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Radical bulk polymerization of N-vinylcaprolactam

✍ Scribed by O. F. Solomon; M. Corciovei; C. Boghin˘

Publisher
John Wiley and Sons
Year
1968
Tongue
English
Weight
341 KB
Volume
12
Category
Article
ISSN
0021-8995

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In this communication, we first used [60]fullerene as initiator to initiate the bulk polymerization of N-vinylcarbazole (NVC) monomer at 70°C (slightly higher than the melting point temperature, 65°C, of NVC). A reasonable polymerization reaction pathway via C 60 -NVC ion-radical pairs is suggested.