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Radical polymerization of N-vinylcaprolactam in homogeneous solution. II

✍ Scribed by O. F. Solomon; D. S. Vasilescu; V. Tǎrǎrescu

Publisher
John Wiley and Sons
Year
1969
Tongue
English
Weight
227 KB
Volume
13
Category
Article
ISSN
0021-8995

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✦ Synopsis

The polymerization of N-vinylcaprolactam in toluene, dioxane, chlorobeneene, dimethylformamide, and ethylene carbonate with various peroxides, perbenzoates and azobisisobutyronitrile as initiators at 60-8OoC, was studied. Under these conditions azobisisobutyronitrile and terkbutyl perbenzoate have satisfactory activity as initiators. Under these conditions N-vinylcaprolactam polymerization in homogeneous solution is f h t order towards the monomer and 0.5 order towards the initiators.

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