The photosensitized polymerization of styrene in bulk was investigated in the temperature range of 25-70Β°C with respect to the average rate coefficient of bimolecular chain termination k t , especially its chain length dependence at low conversions, by means of pulsed laser polymerization (PLP). Thr
Temperature dependence of stereospecificity in the radical polymerization of di-n-butyl itaconate in bulk
β Scribed by Tomohiro Hirano; Sachiko Tateiwa; Makiko Seno; Tsuneyuki Sato
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 119 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0887-624X
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An on-line optimizing control scheme has been developed for bulk polymerization of free radical systems. The effects of random errors, as well as one kind of a major disturbance (heating system failure), have been studied. A model-based, inferential state estimation scheme was incorporated to estima
The influence of n,s-dibutylmagnesium on the kinetics of styrene polymerization initiated by sbutyllithium was investigated in cyclohexane at 50 8C. The presence of n,s-dibutylmagnesium, in molar ratios ranging from 0 to 20 with respect to polystyryllithium, leads to a drastic and continuous reducti