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Radical addition of protonated N-chloroamines to olefins

โœ Scribed by Francesco Minisci; Remo Galli; Mirella Cecere

Book ID
104250361
Publisher
Elsevier Science
Year
1966
Tongue
French
Weight
165 KB
Volume
7
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Recently R.S.Neale' ha6 reported that the protonated I-ohloroemines add in good yield8 to oertain substituted olefine,partioularly vinyl chloroderivativee,whereas with unsubstituted olefina the reaotion oocur~ in low yields or doesn't at all.The reaeona adduced for thin

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Homolytic addition reaction of N-halosulfoximides, i.e., diphenyl-N-chloro sulfoximide(i), diphenyl-N-bromosulfoximide(x), and methylphenyl-N-chlorosulfoximide(,$), to such olefins as tert-butylethylene and cyclohexene was found to afford the corresponding N-alkylated sulfoximides, which are presume

Addition of methoxy radicals to olefins
Addition of methoxy radicals to olefins
โœ E. A. Lissi; G. Massiff; A. Villa ๐Ÿ“‚ Article ๐Ÿ“… 1975 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 321 KB

## Abstract The addition of methoxy radicals to several olefins has been studied by a competitive method at 127ยฐC in gas phase. The thermal decomposition of dimethyl peroxide was used as methoxy radical source. The rate of addition to the double bond was measured relative to the oxidation of carbon