๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Sulfoximidoyl radical. Homolytic addition of n-halosulfoximides to olefins

โœ Scribed by Takeshi Akasaka; Naomichi Furukawa; Shigeru Oae

Book ID
104237733
Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
209 KB
Volume
20
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

โœฆ Synopsis

Homolytic addition reaction of N-halosulfoximides, i.e., diphenyl-N-chloro sulfoximide(i), diphenyl-N-bromosulfoximide(x), and methylphenyl-N-chlorosulfoximide(,$), to such olefins as tert-butylethylene and cyclohexene was found to afford the corresponding N-alkylated sulfoximides, which are presumed to be formed via the initial addition of the sulfoximidoyl radical. Aminyl radicals or acylaminyl radicals generated from the corresponding N-haloamines or N-haloamides, e.g., succinimidoyl radical, are known to react with olefins to afford either the

๐Ÿ“œ SIMILAR VOLUMES

Radical addition of protonated N-chloroa
Radical addition of protonated N-chloroamines to olefins
โœ Francesco Minisci; Remo Galli; Mirella Cecere ๐Ÿ“‚ Article ๐Ÿ“… 1966 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 165 KB

Recently R.S.Neale' ha6 reported that the protonated I-ohloroemines add in good yield8 to oertain substituted olefine,partioularly vinyl chloroderivativee,whereas with unsubstituted olefina the reaotion oocur~ in low yields or doesn't at all.The reaeona adduced for thin

Addition of methoxy radicals to olefins
Addition of methoxy radicals to olefins
โœ E. A. Lissi; G. Massiff; A. Villa ๐Ÿ“‚ Article ๐Ÿ“… 1975 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 321 KB

## Abstract The addition of methoxy radicals to several olefins has been studied by a competitive method at 127ยฐC in gas phase. The thermal decomposition of dimethyl peroxide was used as methoxy radical source. The rate of addition to the double bond was measured relative to the oxidation of carbon