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Addition of methoxy radicals to olefins

✍ Scribed by E. A. Lissi; G. Massiff; A. Villa

Publisher
John Wiley and Sons
Year
1975
Tongue
English
Weight
321 KB
Volume
7
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

The addition of methoxy radicals to several olefins has been studied by a competitive method at 127Β°C in gas phase. The thermal decomposition of dimethyl peroxide was used as methoxy radical source. The rate of addition to the double bond was measured relative to the oxidation of carbon monoxide. For the addition to ethylene it was obtained that
This rate constant is similar to the one shown by methyl radicals under similar conditions. From the relative rate of addition to several chlorinated and fluorinated olefins it can be concluded that methoxy radicals show very little β€œelectrophilic” character.

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