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First Examples of Intramolecular Addition of Primary Amidyl Radical to Olefins.

✍ Scribed by Philippe Gaudreault; Christian Drouin; Jean Lessard

Publisher
John Wiley and Sons
Year
2006
Weight
16 KB
Volume
37
Category
Article
ISSN
0931-7597

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Addition of methoxy radicals to olefins
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## Abstract The addition of methoxy radicals to several olefins has been studied by a competitive method at 127Β°C in gas phase. The thermal decomposition of dimethyl peroxide was used as methoxy radical source. The rate of addition to the double bond was measured relative to the oxidation of carbon

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**The presence of a negative partial charge on the benzylic carbon atom in the transition state** __(1)__ can be deduced from the experimentally determinable Hammett Ο± values. Alkyl radicals R^Λ™^ are accordingly seen to develop nucleophilic properties during addition to olefins. equation image

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