Stabilization of Radicals by “Capto-Dative” Substitution CC Addition to Radicophilic Olefins

✍ Scribed by Dr. Lucien Stella; Dr. Zdenek Janousek; Dipl.-Ing. Robert Merényi; Prof. Heinz Günter Viehe

• Publisher: John Wiley and Sons
• Year: 1978
• Tongue: English
• Weight: 211 KB
• Volume: 17
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.197806911

✦ Synopsis

Diene complexes which are substituted in the 2-position, or do not bear electron-withdrawing substituents, react less specifically[31. For example, the complex ( 9 ) yields a mixture of the isomericenones ( l o ) , ( l l ) , and (12), with the 1,4-addition of hydrogen strongly predominating.