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Radical addition of fluoroalkyl iodides to vinyltrimethylsilane in the presence of copper and stereospecific synthesis of corresponding olefins

โœ Scribed by Chen Qing-yun; Yang Zhen-yu; Rong Da-qing

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
43 KB
Volume
29
Category
Article
ISSN
0022-1139

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๐Ÿ“œ SIMILAR VOLUMES

Free radical addition of haloalkanes to
Free radical addition of haloalkanes to polymer bound olefins and its application to the solid-phase synthesis of pyrethroids
โœ H.M.S Kumar; P.Pawan Chakravarthy; M Shesha Rao; P.Sunder Ram Reddy; J.S Yadav ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 306 KB

Polymer bound olefins undergo free radical initiated 1,2-addition when reacted with a variety of haloalkanes. The strategy could be applied successfully to the solid-phase synthesis of dihaloethenylcyclopropane carboxylic acids which are the key fragments of synthetic pyrethroids.