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Radical additions to olefins in the presence of iodobenzenediacetate: an easy route to alkyl dithiocyanates

✍ Scribed by Antonella De Mico; Roberto Margarita; Andrea Mariani; Giovanni Piancatelli


Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
168 KB
Volume
37
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES


Polar Effects in the Addition of Alkyl R
✍ Priv.-Doz. Dr. Bernd Giese; Dipl.-Chem. JΓΌrgen Meister πŸ“‚ Article πŸ“… 1977 πŸ› John Wiley and Sons 🌐 English βš– 198 KB πŸ‘ 2 views

**The presence of a negative partial charge on the benzylic carbon atom in the transition state** __(1)__ can be deduced from the experimentally determinable Hammett Ο± values. Alkyl radicals R^Λ™^ are accordingly seen to develop nucleophilic properties during addition to olefins. equation image