Quinolinium trichloro(quinoline-κN)cobaltate(II)
✍ Scribed by Pan, Tian-Tian ;Xu, Duan-Jun
- Book ID
- 104481316
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 293 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.004 A Ê R factor = 0.032 wR factor = 0.079 Data-to-parameter ratio = 14.3
For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
In the structure of the title complex, [CoCl 2 (C 9 H 7 N) 2 ], the Co atom is coordinated by two chloride ligands and by two N atoms from two quinoline ligands. The geometry around the Co atom is slightly distorted tetrahedral, with CoÐN bond lengths of 2.0697 (18) A Ê , CoÐCl bond lengths of 2.244
Figure 1 ORTEP-3 (Farrugia, 1997) view of (I), with 50% probability displacement ellipsoids. H atoms are shown as spheres with arbitrary radii. metal-organic papers m902 Victor B. Rybakov et al. [CuCl 2 (C 20 H 18 N 2 O 2 )] Acta Cryst. (2004). E60, m901±m903
As a result of problems with the data sets and incorrect atom assignments, 41 papers by H. Zhong et al. are retracted. Full details of all the articles are given in Table 1.
trans(Cl,N amino )-Chloro(dimethyl sulfoxide-jS)[tris(2-pyridylmethyl)amine-j 4 N]ruthenium(II) trichlorotris(dimethyl sulfoxide-jS)ruthenate(II)
The title compound, [Co(C 12 H 27 O 3 SSi) 2 (C 7 H 9 N)(NH 3 )], was obtained by the reaction of dimeric [Co{SSi(O t Bu) 3 } 2 (NH 3 )] 2 with 2-ethylpyridine. The Co II atom is coordinated by two S atoms from two silanethiolate ligands and two N atoms, one from ammonia and one from a 2-ethylpyridi