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Monoclinic form of di­chloro­bis­(quinoline-N)­cobalt(II)

✍ Scribed by Wang, Wenguo ;Huang, Deguang ;Zhu, Hongping ;Chen, Changneng ;Liu, Qiutian

Publisher
International Union of Crystallography
Year
2001
Tongue
English
Weight
360 KB
Volume
57
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the structure of the title complex, [CoCl 2 (C 9 H 7 N) 2 ], the Co atom is coordinated by two chloride ligands and by two N atoms from two quinoline ligands. The geometry around the Co atom is slightly distorted tetrahedral, with CoÐN bond lengths of 2.0697 (18) A Ê , CoÐCl bond lengths of 2.2445 (7) A Ê , and NÐCoÐN and ClÐCoÐCl bond angles of 107.16 (10) and 113.44 (4) , respectively. The molecule has twofold rotation symmetry.

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Di­chloro­bis(2-methyl­quinoline N-oxide
Di­chloro­bis(2-methyl­quinoline N-oxide-κO)copper(II)
✍ Rybakov, Victor B. ;Semenova, Tatiana A. ;Aleshina, Lyudmila A. ;Andreev, Vladim 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 206 KB

Figure 1 ORTEP-3 (Farrugia, 1997) view of (I), with 50% probability displacement ellipsoids. H atoms are shown as spheres with arbitrary radii. metal-organic papers m902 Victor B. Rybakov et al. [CuCl 2 (C 20 H 18 N 2 O 2 )] Acta Cryst. (2004). E60, m901±m903