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Quasiclassical trajectory study of colinear Cl− + HBr → HCl + Br−

✍ Scribed by Sally Chapman

Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
463 KB
Volume
80
Category
Article
ISSN
0009-2614

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✦ Synopsis

Energy drstrrbutions in the products of the ion-molecule reaction Cl-+ HBr -HCI + Br-have been studied using quasiclassical trajectories on a semi-empirical collinear potential energy surface. Vibrational energy is favored in the products. While some trajectories are long-lived, the kinematic factor of the light central atom prevents effective energy redistribution The study of the kinetics of ion-molecule reactions has a long history with important contemporary applications in combustion,

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