Reaction and relaxation of vibrationally excited molecules: a classical trajectory study of Br + HCl(υ′) and Br + DCl(υ′) collisions

Cavity ring-down study of BrO radicals:

Cavity ring-down study of BrO radicals: Kinetics of the Br + O3 reaction and rate of relaxation of vibrationally excited BrO by collisions with N2 and O2

✍ Yuki Ninomiya; Satoshi Hashimoto; Masahiro Kawasaki; Timothy J. Wallington 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 256 KB 👁 2 views

Cavity ring-down (CRD) techniques were used to study the kinetics of the reaction of Br atoms with ozone in 1-205 Torr of either N 2 or O 2 , diluent at 298 K. By monitoring the rate of formation of BrO radicals, a value of k(Br ϩ O 3 ) ϭ (1.2 Ϯ 0.1) ϫ 10 Ϫ12 cm 3 molecule Ϫ1 s Ϫ1 was established th