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A quasiclassical trajectory study of the heavy-light-heavy Cl-HCl reaction: Oscillating energy-dependent cross sections

✍ Scribed by M. Baer; I. Last


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
245 KB
Volume
119
Category
Article
ISSN
0009-2614

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✦ Synopsis


Cross sections are obmlned in a quasiclassical trajectory swdy of the reacrion HCI + Cl' + HCI'+ Cl. The mam purpose is lo find out whether pnrlial cross seclions uhlch rekr only LO a cernln angular range of Ihe c<nLer-of-mass scdrlering angle B oscillale as a runclion of energy. The swdy was carried out for the energy range 0 3 Q E, 4 2.0 cV and retealed swong oscillahons for the angular range 160" c 0 4 z Smce the crou seaions are 1101 small. II IS likely that this heha\ior IS derectable in molecular beam enpcrimenw.