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A quasi-classical trajectory study of molecular desorption: Cl+H…surface→HCl+surface

✍ Scribed by Shlomo Ron; Michael Baer

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
383 KB
Volume
146
Category
Article
ISSN
0009-2614

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✦ Synopsis

This paper describes a quasiclassical trajectory study of a molecular desorption process between a gaseous chlorine atom and an adsorbed hydrogen atom on a corrugated surface. Opacity functions, vibrational and rotational energy distributions and integral cross sections were calculated for the energy range 0.2 <E< 1.9 eV. The results were found to be significantly different from those obtained in gas-phase atom-molecule interactions but similar to those obtained for gas-phase ion-molecule interactions.

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