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Pyrolysis of Esters. XIX. Synthesis of Racemic and Optically Active 3-Methyl-1-pentene 1-3

✍ Scribed by BAILEY, WILLIAM J.; YATES, EDWIN T.


Book ID
127365441
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
479 KB
Volume
26
Category
Article
ISSN
0022-3263

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## Abstract 3‐Methyl‐1‐pentene was deuterioformylated in the presence of rhodium‐catalyst. The extent of attack on each face of the olefin was evaluated from the diastereomeric composition of both positional isomers obtained as the products. An overall preferred attack on the __si‐si__ face of the