Rhodium-Catalyzed Deuterioformylation of 3-Methyl-1-pentene

✍ Scribed by Annibale Stefani; Dante Tatone; Piero Pino

• Book ID: 102251913
• Publisher: John Wiley and Sons
• Year: 1979
• Tongue: German
• Weight: 284 KB
• Volume: 62
• Category: Article
• ISSN: 0018-019X
• DOI: 10.1002/hlca.19790620419

✦ Synopsis

Abstract

3‐Methyl‐1‐pentene was deuterioformylated in the presence of rhodium‐catalyst. The extent of attack on each face of the olefin was evaluated from the diastereomeric composition of both positional isomers obtained as the products. An overall preferred attack on the si‐si face of the (S)‐enantiomer, and on the re‐re face of the (R)‐enantiomer was found.