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Isotactic polymerization of 3-methyl-1-pentene: enantioselectivity and diastereoselectivity

✍ Scribed by Zambelli, Adolfo; Ammendola, Paolo; Sacchi, Maria Carmela; Locatelli, Paolo; Zannoni, Giulio


Book ID
127341781
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
934 KB
Volume
16
Category
Article
ISSN
0024-9297

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## Abstract 3‐Methyl‐1‐pentene was deuterioformylated in the presence of rhodium‐catalyst. The extent of attack on each face of the olefin was evaluated from the diastereomeric composition of both positional isomers obtained as the products. An overall preferred attack on the __si‐si__ face of the