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Pyridine Group Assisted Addition of Diazo-Compounds to Imines in the 3-CC Reaction of 2-Aminopyridines, Aldehydes, and Diazo-Compounds

✍ Scribed by Gulevich, Anton V.; Helan, Victoria; Wink, Donald J.; Gevorgyan, Vladimir


Book ID
118742277
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
517 KB
Volume
15
Category
Article
ISSN
1523-7060

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✍ Raquel Alguacil; Francisco FariΓ±a; M Victoria MartΓ­n; M.Carmen Paredes πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 439 KB

The 1,3 dipolar cycloadditions of diazomethane and ethyl diazoacetate with differently substituted 5-mlfur-2(5/-/)-furanones (1-6) are rcpone~ Cycloaddition of diazomethane occurs in a regio-and ~Β’ manner to give the ~ed adducts 9-14, in good yield. The cycloaddition with ethyl diazoat~ate occurs al