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Heterocyclization of compounds containing diazo and cyano groups. 3. Two pathways in the cyclization of 2-diazo-2-cyanoacetic acid derivatives under the influence of bases

โœ Scribed by Yu. M. Shafran; V. A. Bakulev; V. S. Mokrushin; S. G. Alekseev; A. T. Lebedev; P. A. Sharbatyan


Book ID
112361528
Publisher
Springer US
Year
1986
Tongue
English
Weight
722 KB
Volume
22
Category
Article
ISSN
0009-3122

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ฮฒ-Oxy-ฮฑ-diazo-carbonyl compounds. Part 5
โœ Francisco Sarabia; Fidel Jorge Lรณpez-Herrera ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 79 KB

Reactions of ethyl 2-diazoacetate with aldehydo sugars and monosaccharide derivatives in their hemiacetal form are reported. The use of diethyl zinc led to an improvement of yields and shorter reaction times compared with neutral conditions as previously described. The resulting products represent p