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Heterocyclization of compounds containing diazo and cyano groups. 5. 2-Diazo-2-cyanoacetazide in the synthesis of 5-halo-1H-1,2,3-triazone-4-carboxylic acid azides

✍ Scribed by M. Yu. Kolobov; V. A. Bakulev; V. S. Mokrushin; A. T. Lebedev


Publisher
Springer US
Year
1987
Tongue
English
Weight
444 KB
Volume
23
Category
Article
ISSN
0009-3122

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Pseudoesters and derivatives. Part 37. 1
✍ Raquel Alguacil; Francisco FariΓ±a; M Victoria MartΓ­n; M.Carmen Paredes πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 439 KB

The 1,3 dipolar cycloadditions of diazomethane and ethyl diazoacetate with differently substituted 5-mlfur-2(5/-/)-furanones (1-6) are rcpone~ Cycloaddition of diazomethane occurs in a regio-and ~Β’ manner to give the ~ed adducts 9-14, in good yield. The cycloaddition with ethyl diazoat~ate occurs al