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PtCl 2 -Catalyzed Conversion of 1,6- and 1,7-Enynes to 1-Vinylcycloalkenes. Anomalous Bond Connection in Skeletal Reorganization of Enynes

✍ Scribed by Chatani, Naoto; Furukawa, Naoyuki; Sakurai, Hitoshi; Murai, Shinji

Book ID: 126154439
Publisher: American Chemical Society
Year: 1996
Tongue: English
Weight: 204 KB
Volume: 15
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om950832j

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## Abstract The more electron‐withdrawing the N‐protecting group and the alkene substituent, the slower is the reaction rate of the cycloisomerization of 1,6‐enynes to yield bicyclic products (II) and (IV).