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Highly Selective Skeletal Reorganization of 1,6- and 1,7-Enynes to 1-Vinylcycloalkenes Catalyzed by [RuCl2(CO)3]2

โœ Scribed by Chatani, Naoto; Morimoto, Tsumoru; Muto, Toyoshige; Murai, Shinji


Book ID
126205111
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
239 KB
Volume
116
Category
Article
ISSN
0002-7863

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## Abstract Treatment of 2,2,4,4โ€tetramethylโ€1,5โ€diphenylโ€6,7โ€dithiabicyclo[3.1.1]heptane 6โ€endoโ€oxide (2) with Montmorillonitc K 10 in dichloromethane gave 2,2,โ€4,4โ€tetramethylโ€1,5โ€diphenylโ€7,8โ€dithiaโ€6โ€oxabicycloโ€[3.2.1]octane (6) (11%) with recovery of 2 (87%). Under similar reaction conditions,