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ChemInform Abstract: Effects of Nitrogen and Alkene Substitution on the PtCl2-Catalyzed Cycloisomerization of N-Tethered 1,6-Enyne Precursors to the Triple Reuptake Inhibitor GSK1360707.

✍ Scribed by Vassil Elitzin; Bing Liu; Matthew Sharp; Elie Tabet


Publisher
John Wiley and Sons
Year
2011
Weight
34 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

The more electron‐withdrawing the N‐protecting group and the alkene substituent, the slower is the reaction rate of the cycloisomerization of 1,6‐enynes to yield bicyclic products (II) and (IV).