Pressure dependence of the rate of reaction of OH with HCN
β Scribed by L.F. Phillips
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 166 KB
- Volume
- 57
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
The r&e constant for removal of OH by HCN in an argon or helium carrier decreases with da-reasing pressure below 15 torr (2 kPa), which shows that a stzbiked HCNOH intermediate invofved in the reaction.
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## Abstract Absolute rate constants for the reaction of OH with H~2~S have been measured over the temperature range of 239β425 K using the flash photolysisβresonance fluorescence technique. The results showed that the rate constants deviate slightly from Arrhenius behavior but can still be represen