𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Temperature dependence of the rate constant for the reaction OH + H2S

✍ Scribed by C. L. Lin

Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
274 KB
Volume
14
Category
Article
ISSN
0538-8066

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Absolute rate constants for the reaction of OH with H~2~S have been measured over the temperature range of 239–425 K using the flash photolysis–resonance fluorescence technique. The results showed that the rate constants deviate slightly from Arrhenius behavior but can still be represented adequately by the following Arrhenius equation:

Comparisons with recent literature values are presented.

πŸ“œ SIMILAR VOLUMES

The rate constant of the reaction HO2 +
The rate constant of the reaction HO2 + COCO2 + OH
✍ I. A. Vardanyan; G. A. Sachyan; A. B. Nalbandyan πŸ“‚ Article πŸ“… 1975 πŸ› John Wiley and Sons 🌐 English βš– 449 KB πŸ‘ 1 views

The high-temperature oxidation of formaldehyde in the presence of carbon monoxide was investigated to determine the rate constant of the reaction HOZ + CO = CO:! + OH (10). In the temperature range of 878-952Β°K from the initial parts of the kinetic curves of the HOz radicals and CO, accumulation at

Rate constant for the reaction of OH rad
Rate constant for the reaction of OH radicals with dimethyl sulfide
✍ Yen-Chung Hsu; Dze-Shu Chen; Yuan-Pern Lee πŸ“‚ Article πŸ“… 1987 πŸ› John Wiley and Sons 🌐 English βš– 485 KB πŸ‘ 2 views

The rate constants of the gas phase reaction of OH radicals with dimethyl sulfide (CH3SCH3) over the temperature range 260-393 K have been studied using the discharge flow-resonance fluorescence technique. The rate constants were fitted by the Arrhenius equation k = (11.8 2 2.2) x exp[-(236 2 150)/T

Rate constants for the gas-phase Ξ²-myrce
Rate constants for the gas-phase Ξ²-myrcene + OH and isoprene + OH reactions as a function of temperature
✍ Ronald A. Hites; Andrew M. Turner πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 491 KB

## Abstract Rate constants for the gas‐phase reactions of the hydroxyl radical with the biogenic hydrocarbons, β‐myrcene and isoprene, were measured using the relative rate technique over the temperature range 313–413 K and at ∼1 atm total pressure. OH was produced by the photolysis of H~2~O~2~, an