Pressure dependence of the reaction of OH with HO2NO2
โ Scribed by I. Barnes; V. Bastian; K.H. Becker; E.H. Fink; F. Zabel
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 455 KB
- Volume
- 123
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
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Mixtures of N20, Hz, 0 2 , and trace amounts of NO and NO2 were photolyzed at 213.9 nm, at 245'-328'K, and at about 1 atm total pressure (mostly H2). HO2 radicals are produced from the photolysis and they react as follows: (la) Reaction (lb) is unimportant under all of our reaction conditions. Rea
## Abstract A theoretical analysis of the temperature and pressure dependence of the reaction HO + NO~2~ + M โ๏ธ HONO~2~ + M is made over the temperature range 50โ1400 K and the pressure range 10^โ4^โ10^3^ bar where experimental data are available. The treatment accounts for contributions from anhar
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