✦ LIBER ✦

Pressure and temperature dependence of the OH radical reaction with acetylene

✍ Scribed by R.A. Perry; David Williamson

Publisher: Elsevier Science
Year: 1982
Tongue: English
Weight: 368 KB
Volume: 93
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(82)83703-2

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✦ Synopsis

Absolulc KIIC constants for the rcac11on ofOH WIII acctylcnc wcrc dctcrmmcd at 297 and 419 K for thu 101.d pru~rc\ ol'20-403 Torr usmg a flash photolysa-rcsonancc lluorcsccnre tcchmquc The rate coclTic~cnt k was found to bc pwrurc dcpcndcnt below 200 Torr at both 297 and 429 K, but \a m the high-prcssurc hmellc rctxm abolc a tool prcww of X0 TOW. TIE best fit to the data over the prcssurc and tcmpcrnrurc r,mgc studred wasgwrn by lhc c\pressron k(T,~)b, = I 18 x lo-" C\P[(-327 2 400)/fU~/(3O/p + I). ~11crc /J IS the prcssurc an Torr

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