Preparation of P(III) and P(III/V) Oxides
โ Scribed by Prof. Dr. E. Thilo; Dr. D. Heinz; Dr. K.-H. Jost
- Publisher
- John Wiley and Sons
- Year
- 1964
- Tongue
- English
- Weight
- 117 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
PhCN#iMe3)3 (1) reacts with PhPCI2 in a molar ratio of 2: 3 to give the bicyclic system 2 with a P(V)-P(III)-P(V) unit, characterized by an X-ray structure analysis. Dichlorophenylphosphane reacts with [MetNC(NH&JCI (3) to form 4. The reaction of MeNCN with LiN(SiMe& and PhPCI2 yields 5 containing a
## Abstract For Abstract see ChemInform Abstract in Full Text.
Kinetics of oxidation of phenylhydrazine and p-bromophenylhydrazine by hexacyanoferrate(I1If in acidic medium have been studied. The reactions follow similar kinetics, being first order with respect to both hydrazine and hexacyanoferrate(II1) and inverse first order with respect to the hydrogen ion.