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Preparation of olefins from alcohols by thermal rearrangement of propargylic xanthates

✍ Scribed by Mélanie Fauré-Tromeur; Samir Z Zard

Book ID
104260612
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
216 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis

Upon heating in toluene in the presence of a catalytic amount of collidinium trifluorosulfonate salt, various S-propargylic xanthates derived from secondary alcohols can be easily converted to their corresponding olefins in good yields.

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