𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Olefin Rearrangements. The Equilibrium of Olefins from Pinacolyl Alcohol 1

✍ Scribed by Smith, Robert Kinsel


Book ID
125943523
Publisher
American Chemical Society
Year
1942
Tongue
English
Weight
328 KB
Volume
64
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Preparation of olefins from alcohols by
✍ MΓ©lanie FaurΓ©-Tromeur; Samir Z Zard πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 216 KB

Upon heating in toluene in the presence of a catalytic amount of collidinium trifluorosulfonate salt, various S-propargylic xanthates derived from secondary alcohols can be easily converted to their corresponding olefins in good yields.

1-Methoxy-1-(phenylthio)cyclopropanes fr
✍ M. Bhupathy; Theodore Cohen πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 French βš– 258 KB

The Pummerer rearrangements of cyclopropyl(methoxy)phenylsulfonium salts proceed via sulfur-stabilized carbocations to yield the title compounds. The sulfonium salts were prepared in high yields from olefins via carbene addition, oxidation, and methylation.

ChemInform Abstract: Preparation of Olef
✍ Melanie Faure-Tromeur; Samir Z. Zard πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 32 KB

Preparation of Olefins from Alcohols by Thermal Rearrangement of Propargylic Xanthates. -Thermolysis of propargylic xanthates derived from secondary alcohols in the presence of catalytic amounts of collidinium triflate affords the corresponding olefins in good yields. When the xanthate is located a