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1-Methoxy-1-(phenylthio)cyclopropanes from olefins via the Pummerer rearrangement

✍ Scribed by M. Bhupathy; Theodore Cohen

Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
258 KB
Volume
28
Category
Article
ISSN
0040-4039

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✦ Synopsis

The Pummerer rearrangements of cyclopropyl(methoxy)phenylsulfonium salts proceed via sulfur-stabilized carbocations to yield the title compounds. The sulfonium salts were prepared in high yields from olefins via carbene addition, oxidation, and methylation.

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