Preparation of 3-aza-Cope rearrangement of N-alkyl-N-allyl enamines
β Scribed by Cook, Gregory R.; Stille, John R.
- Book ID
- 121350594
- Publisher
- American Chemical Society
- Year
- 1991
- Tongue
- English
- Weight
- 881 KB
- Volume
- 56
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
Pd(0) complexes catalyze the 3-Aza-Cope rearrangement of N-allylenamines to the corresponding 6,c-unsaturated imines or y,+unsaturated carbonyl compounds in the presence of trifluoroacetic acid as co-catalyst. The Cope rearrangements are of considerable synthetic utility. There have been many report
A 2-aza-Cope rearrangement underlying the more typical reactions of N-acyl-Z-aza-\_I\_\_\_\_\_\_ 1,5-hexadienes has been detected using triethylsilane as an acyliminium ion trap. Hetero-Cope rearrangements have previously been reported for substituted 2-aza-1,5-hexadienes 1 and their iminium ion co