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Microwave-assisted aza-Cope rearrangement of N-allylanilines

✍ Scribed by Israel González; Iria Bellas; Ana Souto; Ramón Rodríguez; Jacobo Cruces

Book ID: 104095006
Publisher: Elsevier Science
Year: 2008
Tongue: French
Weight: 97 KB
Volume: 49
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2008.01.078

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ChemInform Abstract: Microwave-Assisted

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Pd(0) complexes catalyze the 3-Aza-Cope rearrangement of N-allylenamines to the corresponding 6,c-unsaturated imines or y,+unsaturated carbonyl compounds in the presence of trifluoroacetic acid as co-catalyst. The Cope rearrangements are of considerable synthetic utility. There have been many report