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Lewis acid-promoted 3-aza-Cope rearrangement of N-alkyl-N-allylanilines

✍ Scribed by Beholz, Lars G.; Stille, John R.

Book ID
119967609
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
844 KB
Volume
58
Category
Article
ISSN
0022-3263

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Palladium(0) catalyzed 3-aza-cope rearra
Palladium(0) catalyzed 3-aza-cope rearrangement of N-allylenamines
✍ Shun-ichi Murahashi; Yoshiki Makabe πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 French βš– 238 KB

Pd(0) complexes catalyze the 3-Aza-Cope rearrangement of N-allylenamines to the corresponding 6,c-unsaturated imines or y,+unsaturated carbonyl compounds in the presence of trifluoroacetic acid as co-catalyst. The Cope rearrangements are of considerable synthetic utility. There have been many report