Lewis acid and high pressure promoted Diels-Alder cycloadditions of N-alkyl-N-sulfinyl dienophiles
โ Scribed by Scott I. Bell; Steven M. Weinreb
- Book ID
- 108381685
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- French
- Weight
- 204 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Enantioselective hetero Diels-Alder (HDA) reactions of 1,3-cyclohexadiene with benzyl N-sulfinylcarbamate 1a and with N-sulfinyl-p-toluensulfonamide 1b promoted by chiral Ti(IV)-based Lewis acids are reported. The obtained yields and enantiomeric excesses obtained are heavily dependant on the mode o
Me2AICI -and TiCl4-catalyzed asymmetric hetero Diels-Alder cycloaddition reactions of 2,4-diphenyl-l-thiabuta-l,3-diene with (S)-N-acryloyl-and (S)-N-crotonoyl-4-benzyl-l,3-oxazolidin-2one dienophiles are described in which not only the sense of the n-facial selectivity but also the degree dramatica