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N-acyliminium ions: detection of a hidden 2-aza-cope rearrangement

โœ Scribed by David J. Hart; Yeun-Min Tsai

Book ID
104241574
Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
184 KB
Volume
22
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

A 2-aza-Cope rearrangement underlying the more typical reactions of N-acyl-Z-aza-_I______ 1,5-hexadienes has been detected using triethylsilane as an acyliminium ion trap.

Hetero-Cope rearrangements have previously been reported for substituted 2-aza-1,5-hexadienes 1 and their iminium ion counterparts, 2.

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