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N-Acyliminium cyclizations via reversible 2-aza-cope rearrangements

โœ Scribed by Hugo Ent; Henk de Koning; W.Nico Speckamp

Book ID
104233306
Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
183 KB
Volume
26
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

The existence of a reversible 2-aza-Cope rearrangement in cyclizations of N-acyliminium ions derived from I'-and 2'-vinyl-N-(3'-butenyl)-5-hydroxy-2-pyrrolidinones is established.

Substituent effects in the rearrangement of N-acyliminium ions of the 2-aza-1,5-hexadienyl type A have previously been described in reports from our laboratory' and the Hart group2.

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