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Preparation of [18O]-chlorocarbonylsulfenyl chloride

✍ Scribed by Andrew W. Mott; Steven J. Eastep; Urszula Słomczynska; George Barany

Publisher
John Wiley and Sons
Year
1984
Tongue
French
Weight
340 KB
Volume
21
Category
Article
ISSN
0022-2135

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✦ Synopsis

180]-Chlorocarbonylsulfenyl chloride with an isotopic purity of 92% was prepared in three steps starting with the [180]-hydrolysis of 2-ethyl-l,3-dioxolane to [' 80]-propanal, which was then converted to [180]-g-1 -methylpropyl ?-methyl dithiocarbonate, which was then chlorinated to give the title compound.

Distilled yields for the three steps were 57%, 49%, and 40% respectively.

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