Attempts to homocouple 1,3-bis(2-hydroxyhexafluoro-2-propyl)-5iodobenzene (diol iodide) with copper fail to give the desired biphenyl tetrol. However, the dimethyl ether derivative of the diol iodide reacts smoothly with copper to give the biphenyl tetramethyl ether in good yields. The diacetate der
Preparation of 1.3.5-tris(2-hydroxyhexafluoro-2-propyl) benzene and some of its derivatives
β Scribed by Robert L. Soulen; James R. Griffith
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 371 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0022-1139
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β¦ Synopsis
Grignard and lithium exchange methods have been used to prepare the polyfluoro alcohol, 1,3,5-tris(2-hydroxyhexafluoro-2-propyl)benzene.
Preparation of the tris glycidyl ether of this alcohol and other derivatives are reported.
π SIMILAR VOLUMES
Chelating properties of 1,3-bis(2-hydroxyhexafluoro-2-propyllbenzene (1,3-BHPB) and 1,4-bis(2-hydroxyhexafluoro-2-propyllbenzene (1,4-BHPB) have been investigated. We reported
Described herein is a cobalt-mediated cyclooligomerization of mono-and di(6-azulenyl)acetylenes to afford 1,3,5-and 1,2,4-tri(6-azulenyl)benzene derivatives and (h 5 -cyclopentadienyl)[tetra-and di(6-azulenyl)cyclobutadiene]cobalt complexes. The redox behavior of these novel tri(6-azulenyl)benzene d
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