Acyl chlorides are split into acyl and chlorine radicals by light of wavelength 254 my. Since the dissociation energy of the chlorine-hydrogen bond is considerably larger than that of the acyl-hydrogen bond, substitution of the substrate by acyl radicals is observed on irradiation of acid chlorides.
✦ LIBER ✦
1,3,5-Tris[(2-hydroxy-3,5-diphenyl)phenyl]benzene and its Phenoxyl Radicals
✍ Scribed by Tanja Deckert-Gaudig; Siegfried Hünig; Elmar Dormann; Marc Tibor Kelemen
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 299 KB
- Volume
- 2001
- Category
- Article
- ISSN
- 1434-193X
No coin nor oath required. For personal study only.
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