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The complexes of 1,3-bis(2-hydroxyhexafluoro-2-propyl)benzene and 1,4-bis(2-hydroxyhexafluoro-2-propyl)benzene with 1,4-benzodioxane, 1,4-dioxane, dimethyl sulfoxide and pyridine

โœ Scribed by Janusz J. Sepiol; Robert L. Soulen; Bert Sissom


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
53 KB
Volume
29
Category
Article
ISSN
0022-1139

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โœฆ Synopsis


Chelating properties of 1,3-bis(2-hydroxyhexafluoro-2-propyllbenzene (1,3-BHPB) and 1,4-bis(2-hydroxyhexafluoro-2-propyllbenzene (1,4-BHPB) have been investigated. We reported


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Preparation of 1.3.5-tris(2-hydroxyhexaf
โœ Robert L. Soulen; James R. Griffith ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 371 KB

Grignard and lithium exchange methods have been used to prepare the polyfluoro alcohol, 1,3,5-tris(2-hydroxyhexafluoro-2-propyl)benzene. Preparation of the tris glycidyl ether of this alcohol and other derivatives are reported.

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Attempts to homocouple 1,3-bis(2-hydroxyhexafluoro-2-propyl)-5iodobenzene (diol iodide) with copper fail to give the desired biphenyl tetrol. However, the dimethyl ether derivative of the diol iodide reacts smoothly with copper to give the biphenyl tetramethyl ether in good yields. The diacetate der