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Synthesis and redox behavior of 1,3,5- and 1,2,4-tri(6-azulenyl)benzene derivatives

✍ Scribed by Shunji Ito; Haruki Inabe; Tetsuo Okujima; Noboru Morita; Masataka Watanabe; Nobuyuki Harada; Kimiaki Imafuku

Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
111 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis

Described herein is a cobalt-mediated cyclooligomerization of mono-and di(6-azulenyl)acetylenes to afford 1,3,5-and 1,2,4-tri(6-azulenyl)benzene derivatives and (h 5 -cyclopentadienyl)[tetra-and di(6-azulenyl)cyclobutadiene]cobalt complexes. The redox behavior of these novel tri(6-azulenyl)benzene derivatives and [tetra-and di(6-azulenyl)cyclobutadiene]cobalt complexes examined by cyclic voltammetry is also described.

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