✦ LIBER ✦

Preparation of 1-(9-anthryl)-ethanol and 9-anthryloxirane via catalytic enantioselective reduction of prochiral 9-anthryl ketones

✍ Scribed by I. Reiners; J. Martens

Book ID: 104360934
Publisher: Elsevier Science
Year: 1997
Tongue: English
Weight: 120 KB
Volume: 8
Category: Article
ISSN: 0957-4166
DOI: 10.1016/s0957-4166(96)00476-4

No coin nor oath required. For personal study only.

✦ Synopsis

Enantioselective reduction of prochiral 9-anthryl ketones to the corresponding chiral alcohols proceeds with high enantiomeric excess. The chiral alcohol 1-(9-anthryl)-2-bromo-ethanol can be converted to the corresponding chiral oxirane. (~

📜 SIMILAR VOLUMES

ChemInform Abstract: Preparation of 1-(9

ChemInform Abstract: Preparation of 1-(9-Anthryl)-ethanol and 9-Anthryloxirane via Catalytic Enantioselective Reduction of Prochiral 9-Anthryl Ketones.

✍ I. REINERS; J. MARTENS 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 26 KB

Enantioselective reduction of aryl trifl

Enantioselective reduction of aryl trifluoromethyl ketones with BINAL-H. A preparation of 2,2,2-trifluoro-1-(9-anthryl)ethanol

✍ Chong, J. Michael; Mar, Eduardo K. 📂 Article 📅 1991 🏛 American Chemical Society 🌐 English ⚖ 586 KB

Enantioselective binding of 2,2,2-triflu

Enantioselective binding of 2,2,2-trifluoro-1-(9-anthryl)ethanol on a chiral stationary phase: a theoretical study

✍ Lipkowitz, Kenny B.; Demeter, David A.; Parish, Carol A.; Darden, Thomas. 📂 Article 📅 1987 🏛 American Chemical Society 🌐 English ⚖ 842 KB

New Chiral Borohydride Based Reducing Ag

New Chiral Borohydride Based Reducing Agent: Asymmetric Reduction of 9-Anthryl Trifluoromethyl Ketone and Other Carbonyl Compounds

✍ Maiti, Dilip K.; Bhattacharya, Pranab K. 📂 Article 📅 1998 🏛 Taylor and Francis Group 🌐 English ⚖ 327 KB

ChemInform Abstract: New Chiral Borohydr

ChemInform Abstract: New Chiral Borohydride Based Reducing Agent: Asymmetric Reduction of 9-Anthryl Trifluoromethyl Ketone and Other Carbonyl Compounds.

✍ D. K. MAITI; P. K. BHATTACHARYA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB

New Chiral Borohydride Based Reducing Agent: Asymmetric Reduction of 9-Anthryl Trifluoromethyl Ketone and Other Carbonyl Compounds. -The first report of two chiral borohydride agents, prepared from 1,2-aminoalcohols and NaBH 4 , and their use in the reduction of ketones (I) to the corresponding chir

Influence of Solubilized 2,2,2-Trifluoro

Influence of Solubilized 2,2,2-Trifluoro-1-(9-anthryl)-ethanol and Its Photodimerization on Viscoelasticity in Dilute Aqueous Cetyltrimethylammonium Bromide Solutions

✍ Thomas Wolff; Karl Josef Kerperin 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 442 KB

Aqueous micellar solutions containing cetyltrimethylammonium bromide (CTAB) and solubilized 2,2,2-trifluoro-1-( 9 -anthryl)-ethanol (TFAE) known to exhibit photorheological effects were investigated via (i) oscillatory shear viscometry, (ii) electrically induced birefringence, and (iii) dynamic ligh