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ChemInform Abstract: New Chiral Borohydride Based Reducing Agent: Asymmetric Reduction of 9-Anthryl Trifluoromethyl Ketone and Other Carbonyl Compounds.

✍ Scribed by D. K. MAITI; P. K. BHATTACHARYA


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis


New Chiral Borohydride Based Reducing Agent: Asymmetric Reduction of 9-Anthryl Trifluoromethyl Ketone and Other Carbonyl Compounds. -The first report of two chiral borohydride agents, prepared from 1,2-aminoalcohols and NaBH 4 , and their use in the reduction of ketones (I) to the corresponding chiral alcohols (II) in high yields is presented. -(MAITI, D.