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Preparation and Reactions of Polyfunctional Magnesium Arylcuprates Obtained by an Iodide—Copper Exchange.

✍ Scribed by Xiaoyin Yang; Paul Knochel

Publisher
John Wiley and Sons
Year
2004
Weight
119 KB
Volume
35
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

📜 SIMILAR VOLUMES

Preparation of Highly Functionalized Gri
Preparation of Highly Functionalized Grignard Reagents by an Iodine–Magnesium Exchange Reaction and its Application in Solid-Phase Synthesis
✍ Laure Boymond; Mario Rottländer; Gérard Cahiez; Paul Knochel 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 107 KB 👁 2 views

At -40°C aryl iodides that contain other functional groups can be selectively converted into Grignard reagents, which react with electrophiles such as benzaldehyde in the usual manner [Eq. (a)]. Aryl bromides and iodides that are immobilized as esters on a Wang resin behave analogously.