Direct Preparation of Polyfunctional Amino-Substituted Arylmagnesium Reagents via an Iodine—Magnesium Exchange Reaction.
✍ Scribed by Greta Varchi; Christiane Kofink; David M. Lindsay; Alfredo Ricci; Paul Knochel
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 22 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
At -40°C aryl iodides that contain other functional groups can be selectively converted into Grignard reagents, which react with electrophiles such as benzaldehyde in the usual manner [Eq. (a)]. Aryl bromides and iodides that are immobilized as esters on a Wang resin behave analogously.